MATERIAL SAFETY DATA SHEET Page 1 of 5 Date Issued: 08/13/2009 MSDS No: 706341A Fleet 15w40wt CJ-4/SM 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Fleet 15w40wt CJ-4/SM PRODUCT DESCRIPTION: Motor Oil PRODUCT CODE: 706341A PRODUCT FORMULATION NAME: Fleet 15w40wt CJ-4/SM ACTIVE INGREDIENT(S): Severely Solvent Refined Heavy Paraffinic Petroleum Oil; ETHYLENE- PROPYLENE COPOLYMER (C3H6.C3H4) X; PETROLEUM LUBRICANT CRANKCASE ADDITIVE 24 HR. EMERGENCY TELEPHONE DISTRIBUTOR NUMBERS Avery Oil & Propane Inc. 3700 Rives - Eaton Road Rives Junction MI 49277 CHEMTREC (U.S.): (800) 424-9300 CANUTEC (613) 996-6666 Product Stewardship: 517-569-3366 COMMENTS: To the best of our knowledge, this Material Safety Data Sheet conforms to the requirements of US OSHA 29 CFR 1910.1200, 91/155/EEC and Canadian Hazardous Products Act. 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Yellow to light amber liquid, with mild hydrocarbon odor IMMEDIATE CONCERNS: CAUTION! May cause eye and skin irritation. POTENTIAL HEALTH EFFECTS EYES: No significant effects beyond minor irritation are expected. SKIN: No significant effects beyond minor irritation are expected. SKIN ABSORPTION: Refer to skin effects for any adverse symptoms that may occur from absorption. INGESTION: Gastrointestinal tract irritation and/or discomfort is possible. INHALATION: No significant effects beyond minor respiratory discomfort is expected. MEDICAL CONDITIONS AGGRAVATED: Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure. ROUTES OF ENTRY: Absorption, Inhalation, Ingestion 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Vol. % CAS Severely Solvent Refined Heavy Paraffinic Petroleum Oil ~ 75 64741-88-4 ETHYLENE-PROPYLENE COPOLYMER (C3H6.C3H4) X ~ 14 90107-91-1 PETROLEUM LUBRICANT CRANKCASE ADDITIVE ~ 11 AM#420340 F FFFFl lllle eeeee eeeet tttt 1 11115 5555w wwww4 44440 0000w wwwwt tttt C CCCCJ JJJJ- ----4 4444/ ////S SSSSM MMMM Page 2 of 5 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for 15 minutes. If irritation persists, seek medical attention. SKIN: Wash exposed area with mild soap and water. Get medical attention if irritation develops or persists. INGESTION: Do not induce vomiting. Danger from aspirating into lungs exceeds short term toxic effects. Get immediate medical help. INHALATION: Fresh air should alleviate any respiratory discomfort. If breathing difficulties develop or persist, get medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: > (350°F) COC (Cleveland Open Cup) AUTOIGNITION TEMPERATURE: Not Applicable GENERAL HAZARD: Flammable Liquid, can release vapors that form flammable mixtures at temperatures at or above the flashpoint. "Empty" containers retain product residue (liquid and/or vapor) and can be dagerous. EXTINGUISHING MEDIA: Use dry chemical, foam, or carbon dioxide. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon and noxious fumes. EXPLOSION HAZARDS: Mists or sprays could ignite at temperatures below the indicated flash point. Keep ignition sources, open flames, etc., away from these fumes. FIRE FIGHTING PROCEDURES: Proper respiratory equipment to protect against the hazardous effects of combustion products is recommended. Water in a straight hose stream may cause fire to spread and should be used as a cooling medium only. FIRE FIGHTING EQUIPMENT: Respiratory and eye protection are required for fire fighting personnel. Full protective equipment (Bunker Gear) and self contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small outdoor fires, which may easily be extinguished with a portable fire extinguisher, use of a SCBA may not be required. HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous gases and vapors produced in fire are oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Extinguish posssible sources of ignition and ventilate spill area. Dike area to contain spill and clean up by absorbing on an inert absorbent or other convenient means. Do not flush into sewers or natural waterways. Non-essential personnel should not enter area due to slipping hazards. LARGE SPILL: Contain material as described above and call the local fire or police department for immediate emergency assistance. 7. HANDLING AND STORAGE HANDLING: Keep away from heat, sparks or flame. Where flammable mixtures may be present, equipment safe for such locations should be used. Use clean tools and explosion-proof equipment. When transferring large volumes of product, metal containers, including trucks and tank cars, should be grounded and bonded. These products have a low vapor pressure and are not expected to present an inhalation hazard under normal temperatures and pressures. However, when aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with F FFFFl lllle eeeee eeeet tttt 1 11115 5555w wwww4 44440 0000w wwwwt tttt C CCCCJ JJJJ- ----4 4444/ ////S SSSSM MMMM Page 3 of 5 eyes, skin, clothing and shoes. STORAGE: Store unopened containers under cool, dry and ventilated conditions. Keep away from heat, sparks and flame. STORAGE TEMPERATURE: Ambient SHELF LIFE: THE SHELF LIFE OF THIS PODUCT IS UNDETERMINED, BUT MAY BECOME SUSPECT ONE YEAR FROM THE DATE OF PURCHASE. 8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE GUIDELINESOSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITSOSHA PELACGIH TLVChemical Nameppmmg/m3ppmmg/m3Severely Solvent Refined Heavy Paraffinic Petroleum OilTWA5mg/m35mg/m3 ENGINEERING CONTROLS: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure guidelines, additional ventilation or exhaust systems may be required. Where explosive mixtures may be present, electrical systems safe for such locations must be used. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear safety glasses with side shields or goggles when handling this material. SKIN: To prevent any contact, wear impervious protective clothing such as neoprene or butyl rubber gloves, apron, boots or whole bodysuit, as appropriate. RESPIRATORY: Use NIOSH/MSHA approved respirators when vapors or mist concentrations exceed permissible exposure limits. PROTECTIVE CLOTHING: Chemical resistant boots, apron, etc. as necessary to prevent contamination of clothing and skin contact. WORK HYGIENIC PRACTICES: Good personal hygiene practices should always be followed. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Mild Hydrocarbon Odor APPEARANCE: Clear COLOR: Yellow to light Amber pH: Not Applicable PERCENT VOLATILE: Not Applicable VAPOR PRESSURE: < 1 mmHg at 20°C VAPOR DENSITY: > 1 (Air=1) BOILING POINT: > (500°F) FLASHPOINT AND METHOD: > (350°F) COC (Cleveland Open Cup) F FFFFl lllle eeeee eeeet tttt 1 11115 5555w wwww4 44440 0000w wwwwt tttt C CCCCJ JJJJ- ----4 4444/ ////S SSSSM MMMM Page 4 of 5 SOLUBILITY IN WATER: NIL EVAPORATION RATE: Not Applicable DENSITY: ~ 7.3286 at (60°F) SPECIFIC GRAVITY: ~ 0.880 (water=1) at (60°F) VISCOSITY #1: > 100 SUS at (100°F) 10. STABILITY AND REACTIVITY STABLE: Yes HAZARDOUS POLYMERIZATION: No STABILITY: Stable POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Exposure to excessive heat, open flames and sparks. Avoid conditions that favor the formation of excessive mists and/or fumes. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Carbon when burned. INCOMPATIBLE MATERIALS: Strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION ACUTE ORAL LD50: > 5000 mg/kg (rat) EYE EFFECTS: Low hazard for usual industrial handling or commercial handling by trained personnel. SKIN EFFECTS: No significant effects beyond minor irritation are expected. CARCINOGENICITY IARC: Not listed by IARC NTP: Not listed by NTP. OSHA: Not listed by OSHA SENSITIZATION: Based on best current information, there is no known human sensitization associated with these products. REPRODUCTIVE EFFECTS: Based on best current information, there is no known reproductive toxicity associated with this product. MUTAGENICITY: Experimental evidence suggests that these products do not cause mutagenesis. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: KEEP OUT OF SURFACE WATERS, SEWERS, AND WATERWAYS ENTERING OR LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO THE GENERAL PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR. GENERAL COMMENTS: Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric Oxygen transport into th water. Over time, if not removed, Oxygen depletion in the waterway might be enough to cause a fish kill or create an anaerobic environment. F FFFFl lllle eeeee eeeet tttt 1 11115 5555w wwww4 44440 0000w wwwwt tttt C CCCCJ JJJJ- ----4 4444/ ////S SSSSM MMMM Page 5 of 5 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Conditions of use may cause this material to become a hazardous waste as defined by state or federal law. Use approved treatment, transporters and disposal sites. EMPTY CONTAINER: Keep containers closed when not in use. Do not reuse empty containers. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PRIMARY HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: NONE 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: None known at or greater than 1.0% (0.1% for carcinogens) FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: No CHRONIC: No TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: All intentional ingredients are listed on the TSCA Inventory. 16. OTHER INFORMATION REVISION SUMMARY: New MSDS HMIS RATING HEALTH: ---- 1111 FLAMMABILITY:1111 PHYSICAL HAZARD:0000 PERSONAL PROTECTION:BBBB NFPA CODES1111 1111 0000 MANUFACTURER DISCLAIMER: The information in this MSDS was obtained from sources which we believe are reliable. However, the above information is provided without warranty, expressed or implied, regarding its correctness. The conditions or methods if handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibilty and expressly dislcaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the procuct.